Trifluoroacetic acid → Palladium(II) trifluoroacetate

HRID 745337Notes

Reaction equation

HRID 745337 reaction equation
C([O-])(=O)C.[Pd+2:5].C([O-])(=O)C.[F:10][C:11]([F:16])([F:15])[C:12]([OH:14])=[O:13]>>[F:10][C:11]([F:16])([F:15])[C:12]([O-:14])=[O:13].[Pd+2:5].[F:10][C:11]([F:16])([F:15])[C:12]([O-:14])=[O:13]

Participants

3

Reactant 2

HCID 6422Trifluoroacetic acidHCID 167845palladium(II) acetate

Product 1

HCID 2733347Palladium(II) trifluoroacetate

Procedure

Into 40 ml of distilled trifluoroacetic acid was dissolved 1.0 g of palladium acetate. The solvent was distilled off and an additional 20 ml of trifluoroacetic acid was added and distilled off. The residual solid was dried in facuo at 40° C. to afford 1.3 g of brown product, i.e. palladium (II) trifluoroacetate, mp 210° C. (dec).

Workup

  1. distillationThe solvent was distilled off
  2. additionan additional 20 ml of trifluoroacetic acid was added
  3. distillationdistilled off
  4. customThe residual solid was dried in facuo at 40° C.

Sources & evidence

ORD record
ord-2e3ecdecdb0f41c880082e5674931e29
Source dataset
uspto-grants-1986_07
Patent number
US04598160

Reaction notes

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