Acrylic Acid → Acrylic acid hydroxyethyl acrylate

HRID 747810Notes

Reaction equation

HRID 747810 reaction equation
C1COCC1.[C:6]([OH:10])(=[O:9])[CH:7]=[CH2:8].[C:11]([O:15][CH2:16][CH2:17][OH:18])(=[O:14])[CH:12]=[CH2:13]>C(C(OC(CC)(CC)C)(CC)C)C.CC(N=NC(C#N)(C)C)(C#N)C>[C:6]([OH:10])(=[O:9])[CH:7]=[CH2:8].[C:11]([O:15][CH2:16][CH2:17][OH:18])(=[O:14])[CH:12]=[CH2:13]

Participants

6

Reactant 3

HCID 6581Acrylic AcidHCID 8028TetrahydrofuranHCID 131652-Hydroxyethyl acrylate

Product 1

HCID 86591133Acrylic acid hydroxyethyl acrylateYield 561.5%

Reagents, catalysts & solvents 2

HCID 6547AzobisisobutyronitrileCatalystHCID 12430074DiethylethyletherSolvent

Procedure

To 20 g of THF were added 9 g of acrylic acid, 1 g of hydroxyethyl acrylate and 0.1 g of AIBN. The resulting mixture was reacted at 67° C. for 3 hours. After reaction, the resulting solution was dropped in diethylethyl ether, thereby obtaining 9.1 g of a photoresist polymer of Formula (IVb).

Workup

  1. customThe resulting mixture was reacted at 67° C. for 3 hours
  2. customAfter reaction

Sources & evidence

ORD record
ord-5fa13eb842db4e2191cd6953c7222b04
Source dataset
uspto-grants-2008_07
Patent number
US07399570B2

Reaction notes

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