Bicarbonate Ion → 2,4-Dichloro-6-methoxy-3,5-triazine

HRID 748575Notes

Reaction equation

HRID 748575 reaction equation
[N:1]1[C:8](Cl)=[N:7][C:5]([Cl:6])=[N:4][C:2]=1[Cl:3].[C:10](=O)(O)[O-:11]>CO>[Cl:3][C:2]1[N:4]=[C:5]([Cl:6])[N:7]=[C:8]([O:11][CH3:10])[N:1]=1

Participants

4

Reactant 2

HCID 769Bicarbonate IonHCID 7954Cyanuric chloride

Product 1

HCID 192672,4-Dichloro-6-methoxy-3,5-triazine

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Cyanuric chloride was reacted with methanol in the presence of bicarbonate at 30° C. as described in the literature to give the product: mp 89-91° C. (lit mp 87-89° C., J. R. Dudley, et al, J. Amer. Chem. Soc., 1951, 73, 2986-2990), after recrystallization from heptane. 1H-NMR (CDCl3): δ4.12 (OCH3).

Workup

  1. customto give the product
  2. custommp 89-91° C. (lit mp 87-89° C., J. R. Dudley, et al, J. Amer. Chem. Soc., 1951, 73, 2986-2990), after recrystallization from heptane

Sources & evidence

ORD record
ord-5441bf5d396c40ae9ae40979705f8be2
Source dataset
uspto-grants-2008_07
Patent number
US07399841B1

Reaction notes

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