Dimethyl Sulfoxide → Methyl 5-formyl-2-methylbenzoate

HRID 800075Notes

Reaction equation

HRID 800075 reaction equation
[CH3:20][S:21]([CH3:22])=[O:23].[CH3:24][CH2:25][N:26]([CH2:27][CH3:28])[CH2:29][CH3:30].[Cl:14][C:15]([C:16]([Cl:17])=[O:18])=[O:19].[Cl:31][CH2:32][Cl:33].[OH:1][CH2:2][c:3]1[cH:4][cH:5][c:6]([CH3:13])[c:7]([C:8](=[O:9])[O:10][CH3:11])[cH:12]1>>[O:1]=[CH:2][c:3]1[cH:4][cH:5][c:6]([CH3:13])[c:7]([C:8](=[O:9])[O:10][CH3:11])[cH:12]1

Participants

6

Reactant 5

HCID 679Dimethyl SulfoxideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 65578Oxalyl chlorideHCID 6850259472985-24-1

Product 1

HCID 19700886Methyl 5-formyl-2-methylbenzoate

Sources & evidence

ORD record
ord-4e0b907ba0ee4a6b862d777200168350
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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