4,4'-Dimethoxybenzophenone → p,p'-Dimethoxybenzhydryl alcohol

反応式

C1(C2C=CC=CC=2CO)C2C(=CC=CC=2)C=CC=1.[CH3:19][O:20][C:21]1[CH:36]=[CH:35][C:24]([C:25]([C:27]2[CH:32]=[CH:31][C:30]([O:33][CH3:34])=[CH:29][CH:28]=2)=[O:26])=[CH:23][CH:22]=1.[BH4-].[Na+]>>[CH3:34][O:33][C:30]1[CH:29]=[CH:28][C:27]([CH:25]([C:24]2[CH:35]=[CH:36][C:21]([O:20][CH3:19])=[CH:22][CH:23]=2)[OH:26])=[CH:32][CH:31]=1

参加物

反応物 3

HCID 70324,4'-Dimethoxybenzophenone

HCID 4311764Sodium borohydride

HCID 57154374[(Naphthyl)phenyl]methanol

生成物 1

HCID 69768p,p'-Dimethoxybenzhydryl alcohol

実験手順

With the same method as for Compound 13, 4,4′-dimethoxybenzophenone (Aldrich) and sodium borohydride (Wako Pure Chemical Industries, ltd.) were used, to thereby obtain the title compound.

出典と根拠

ORDレコード: ord-aaada946d22b4da7963e457f5de2db6a
出典データセット: uspto-grants-2014_09
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08846012B2

反応ノート

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