Acetate → p-Chlorophenyl allyl ether

HRID 804937Notes

Reaction equation

HRID 804937 reaction equation
[C:36]([O-:37])(=[O:38])[CH3:39].[C:41]([O-:42])(=[O:43])[CH3:44].[C:9](=[O:10])([O:14][CH3:15])[O:16][CH2:11][CH:12]=[CH2:13].[OH:1][c:2]1[cH:3][cH:4][c:5]([Cl:6])[cH:7][cH:8]1.[Pd+2:40].[c:17]1([P:18]([c:19]2[cH:20][cH:21][cH:22][cH:23][cH:24]2)[c:25]2[cH:26][cH:27][cH:28][cH:29][cH:30]2)[cH:31][cH:32][cH:33][cH:34][cH:35]1>>[O:1]([c:2]1[cH:3][cH:4][c:5]([Cl:6])[cH:7][cH:8]1)[CH2:13][CH:12]=[CH2:11]

Participants

6

Reactant 5

HCID 175Acetate2×HCID 46844-ChlorophenolHCID 11776TriphenylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 534788Methyl 2-propen-1-yl carbonate

Product 1

HCID 257946p-Chlorophenyl allyl ether

Sources & evidence

ORD record
ord-5994afbc2ee744d0956989eda75dac01
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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