Dimethylformamide → [4-(4-Bromobut-2-enoxy)-2-hydroxyphenyl]-(4-bromophenyl)methanone

HRID 804977Notes

Reaction equation

HRID 804977 reaction equation
[Br:18][CH2:19][CH:20]=[CH:21][CH2:22][Br:23].[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8](=[O:9])[c:10]2[c:11]([OH:17])[cH:12][c:13]([OH:16])[cH:14][cH:15]2)[cH:6][cH:7]1.[Li+:24].[Li+:25].[O-:26][C:27](=[O:28])[O-:29].[O:30]=[CH:31][N:32]([CH3:33])[CH3:34]>>[Br:1][c:2]1[cH:3][cH:4][c:5]([C:8](=[O:9])[c:10]2[c:11]([OH:17])[cH:12][c:13]([O:16][CH2:22][CH:21]=[CH:20][CH2:19][Br:18])[cH:14][cH:15]2)[cH:6][cH:7]1

Participants

6

Reactant 5

HCID 6228DimethylformamideHCID 131802-Butene, 1,4-dibromo-HCID 19660Carbonate IonHCID 28486Lithium ion2×HCID 11066277(4-Bromo-phenyl)-(2,4-dihydroxyphenyl)-methanone

Product 1

HCID 70162219[4-(4-Bromobut-2-enoxy)-2-hydroxyphenyl]-(4-bromophenyl)methanone

Sources & evidence

ORD record
ord-4640e130d47b40ca91ce19e64210b466
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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