Dimethyl Sulfoxide → 2-Bromo-5-ethoxybenzaldehyde

HRID 808212Notes

Reaction equation

HRID 808212 reaction equation
[Br:1][c:2]1[c:3]([CH:4]=[O:5])[cH:6][c:7]([OH:10])[cH:8][cH:9]1.[C:14](=[O:15])([O-:16])[O-:17].[CH3:20][S:21]([CH3:22])=[O:23].[CH3:25][CH2:26][O:27][C:28]([CH3:29])=[O:30].[Cs+:18].[Cs+:19].[I:11][CH2:12][CH3:13].[OH2:24]>>[Br:1][c:2]1[c:3]([CH:4]=[O:5])[cH:6][c:7]([O:10][CH2:12][CH3:13])[cH:8][cH:9]1

Participants

8

Reactant 7

HCID 679Dimethyl SulfoxideHCID 962WaterHCID 6340IodoethaneHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 3871792-Bromo-5-hydroxybenzaldehyde

Product 1

HCID 30164192-Bromo-5-ethoxybenzaldehyde

Sources & evidence

ORD record
ord-809eae132825456e83382446abca6585
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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