Dimethyl Sulfoxide → 4-Bromo-1-(methanesulfonyl)-2-methylbenzene

HRID 809311Notes

Reaction equation

[Br:1][c:2]1[cH:3][c:4]([CH3:9])[c:5]([I:8])[cH:6][cH:7]1.[CH3:10][S:11](=[O:12])[OH:13].[CH3:17][S:18]([CH3:19])=[O:20].[Cu:15][I:16].[Na:14]>>[Br:1][c:2]1[cH:3][c:4]([CH3:9])[c:5]([S:11]([CH3:10])(=[O:12])=[O:13])[cH:6][cH:7]1

Participants

Reactant 5

HCID 679Dimethyl Sulfoxide

HCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)

HCID 87251Methanesulfinic acid

HCID 27246015-Bromo-2-iodotoluene

HCID 5360545Sodium

Product 1

HCID 206167654-Bromo-1-(methanesulfonyl)-2-methylbenzene

Sources & evidence

ORD record: ord-4092ac50ba92404f8f1daa79f9bb1e88
Source dataset: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

Reaction notes

Loading…