Ammonia → Trimethylsilyl benzoate

HRID 812621Notes

Reaction equation

HRID 812621 reaction equation
[CH3:1][SiH:2]([CH3:3])[N:8]([Si:4]([CH3:5])([CH3:6])[CH3:7])[CH3:9].[Cl:32][CH2:33][Cl:34].[NH3:31].[O:19]=[C:20]1[c:21]2[c:22]([cH:23][cH:24][cH:25][cH:26]2)[S:27](=[O:28])(=[O:29])[NH:30]1.[OH:10][C:11](=[O:12])[c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1>>[Si:4]([CH3:5])([CH3:6])([CH3:7])[O:12][C:11](=[O:10])[c:13]1[cH:14][cH:15][cH:16][cH:17][cH:18]1

Participants

6

Reactant 5

HCID 222AmmoniaHCID 243Benzoic AcidHCID 5143SaccharinHCID 6344DichloromethaneHCID 589711N-dimethylsilyl-N-trimethylsilylmethanamine

Product 1

HCID 74955Trimethylsilyl benzoate

Sources & evidence

ORD record
ord-1e6f88844bf744e8953ccde9a09ca1c1
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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