Acetate → 4-ethyl-8-methoxy-1H-pyrano[3,4-c]pyridine

HRID 815898Notes

Reaction equation

HRID 815898 reaction equation
[C:16](=[O:17])([O-:18])[O-:19].[CH2:1]([CH:2]=[CH:3][CH3:4])[O:5][CH2:6][c:7]1[c:8]([O:14][CH3:15])[n:9][cH:10][cH:11][c:12]1[I:13].[CH3:23][CH2:24][CH2:25][CH2:26][N+:27]([CH2:28][CH2:29][CH2:30][CH3:31])([CH2:32][CH2:33][CH2:34][CH3:35])[CH2:36][CH2:37][CH2:38][CH3:39].[CH3:49][N:50]([CH3:51])[CH:52]=[O:53].[Cl-:22].[K+:20].[K+:21].[O-:41][C:42]([CH3:43])=[O:44].[O-:45][C:46]([CH3:47])=[O:48].[Pd+2:40]>>[CH:1]1=[C:2]([CH2:3][CH3:4])[c:12]2[c:7]([c:8]([O:14][CH3:15])[n:9][cH:10][cH:11]2)[CH2:6][O:5]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 312ChlorideHCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 544155093-(But-2-enyloxymethyl)-4-iodo-2-methoxypyridine

Product 1

HCID 106315694-ethyl-8-methoxy-1H-pyrano[3,4-c]pyridine

Sources & evidence

ORD record
ord-c1f6608d79404d7fb0d15769b1f01eec
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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