Potassium Cation → 6-Iodoisoquinoline

HRID 815994Notes

Reaction equation

HRID 815994 reaction equation
[Br:1][c:2]1[cH:3][c:4]2[cH:5][cH:6][n:7][cH:8][c:9]2[cH:10][cH:11]1.[CH2:14]([O:15][CH2:16][CH3:17])[CH3:18].[CH3:22][N:23]([CH3:24])[CH:25]=[O:26].[Cl:19][CH2:20][Cl:21].[Cu:27][I:28].[I-:13].[K+:12]>>[c:2]1([I:13])[cH:3][c:4]2[cH:5][cH:6][n:7][cH:8][c:9]2[cH:10][cH:11]1

Participants

8

Reactant 7

HCID 813Potassium CationHCID 3283Diethyl EtherHCID 6228DimethylformamideHCID 6344DichloromethaneHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 30165Iodide IonHCID 3136816-Bromoisoquinoline

Product 1

HCID 126795216-Iodoisoquinoline

Sources & evidence

ORD record
ord-90d696c60cfc420e89bcce953d42e272
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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