Potassium Cation → 4-(Benzyloxy)-4'-bromo-1,1'-biphenyl

HRID 818284Notes

Reaction equation

HRID 818284 reaction equation
[Br:1][CH2:2][c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1.[Br:9][c:10]1[cH:11][cH:12][c:13](-[c:16]2[cH:17][cH:18][c:19]([OH:22])[cH:20][cH:21]2)[cH:14][cH:15]1.[C:23](=[O:24])([O-:25])[O-:26].[CH2:29]([C:30]([CH3:31])=[O:32])[CH3:33].[K+:27].[K+:28].[O:34]1[CH2:35][CH2:36][CH2:37][CH2:38]1>>[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[O:22][c:19]1[cH:18][cH:17][c:16](-[c:13]2[cH:12][cH:11][c:10]([Br:9])[cH:15][cH:14]2)[cH:21][cH:20]1

Participants

7

Reactant 6

HCID 813Potassium Cation2×HCID 6569Methyl Ethyl KetoneHCID 7498Benzyl BromideHCID 8028TetrahydrofuranHCID 19660Carbonate IonHCID 950934-Bromo-4'-hydroxybiphenyl

Product 1

HCID 224657734-(Benzyloxy)-4'-bromo-1,1'-biphenyl

Sources & evidence

ORD record
ord-6f99fcf59b7942f491bb0dabce5202c1
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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