HRID819246

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID8003

Pentane

C5H12

HCID8028

Tetrahydrofuran

C4H8O

结构：c1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID70672

Benzyltriphenylphosphonium

C25H22P+

结构：COc1ccc(S(=O)(=O)N2CCCCC(C=O)C2C(=O)OC(C)(C)C)cc1

HCID53920336

未命名化合物

HCID178418339

Butyllithium

C4H9Li

PRODUCTS

生成物

结构：COc1ccc(S(=O)(=O)N2CCCCC(C=Cc3ccccc3)C2C(=O)OC(C)(C)C)cc1

HCID54375462

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4bce452fbb7c4c39ae3e4a951163138d
来源数据集: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D
来源说明: Test data from https://doi.org/10.1039/C8SC04228D

反应 SMILES

[Br-:1].[C:33]([CH3:34])([CH3:35])([CH3:36])[O:37][C:38](=[O:39])[CH:40]1[N:41]([S:49](=[O:50])(=[O:51])[c:52]2[cH:53][cH:54][c:55]([O:58][CH3:59])[cH:56][cH:57]2)[CH2:42][CH2:43][CH2:44][CH2:45][CH:46]1[CH:47]=[O:48].[CH2:28]([Li:29])[CH2:30][CH2:31][CH3:32].[CH2:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)[P+:9]([c:10]1[cH:11][cH:12][cH:13][cH:14][cH:15]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)[c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[CH2:60]1[O:61][CH2:62][CH2:63][CH2:64]1.[CH3:65][CH2:66][CH2:67][CH2:68][CH3:69]>>[CH:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)=[CH:47][CH:46]1[CH:40]([C:38]([O:37][C:33]([CH3:34])([CH3:35])[CH3:36])=[O:39])[N:41]([S:49](=[O:50])(=[O:51])[c:52]2[cH:53][cH:54][c:55]([O:58][CH3:59])[cH:56][cH:57]2)[CH2:42][CH2:43][CH2:44][CH2:45]1