Acetate → 4-ethyl-8-methoxy-1H-pyrano[3,4-c]pyridine

HRID 820246Notes

Reaction equation

HRID 820246 reaction equation
[C:16](=[O:17])([O-:18])[O-:19].[C:40]([O-:41])(=[O:42])[CH3:43].[C:45]([O-:46])(=[O:47])[CH3:48].[CH2:1]([CH:2]=[CH:3][CH3:4])[O:5][CH2:6][c:7]1[c:8]([O:14][CH3:15])[n:9][cH:10][cH:11][c:12]1[I:13].[CH2:23]([N+:24]([CH2:25][CH2:26][CH2:27][CH3:28])([CH2:29][CH2:30][CH2:31][CH3:32])[CH2:33][CH2:34][CH2:35][CH3:36])[CH2:37][CH2:38][CH3:39].[CH3:49][N:50]([CH3:51])[CH:52]=[O:53].[Cl-:22].[K+:20].[K+:21].[Pd+2:44]>>[CH:1]1=[C:2]([CH2:3][CH3:4])[c:12]2[c:7]([c:8]([O:14][CH3:15])[n:9][cH:10][cH:11]2)[CH2:6][O:5]1

Participants

9

Reactant 8

HCID 175Acetate2×HCID 312ChlorideHCID 813Potassium Cation2×HCID 6228DimethylformamideHCID 16028TetrabutylammoniumHCID 19660Carbonate IonHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 544155093-(But-2-enyloxymethyl)-4-iodo-2-methoxypyridine

Product 1

HCID 106315694-ethyl-8-methoxy-1H-pyrano[3,4-c]pyridine

Sources & evidence

ORD record
ord-d9f22135d57d4171a1ea796bfde71dc7
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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