Diethyl Ether → 5-(1-Benzylindol-3-yl)-2,4-pentadienal

HRID 825567Notes

Reaction equation

HRID 825567 reaction equation
[Al+3:32].[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[n:8]1[cH:9][c:10]([CH:17]=[CH:18][CH:19]=[CH:20][C:21](=[O:22])[O:23][CH2:24][CH3:25])[c:11]2[cH:12][cH:13][cH:14][cH:15][c:16]12.[CH3:26][CH2:27][O:28][CH2:29][CH3:30].[H-:31].[H-:34].[H-:35].[H-:36].[Li+:33].[O:37]1[CH2:38][CH2:39][CH2:40][CH2:41]1>>[CH2:1]([c:2]1[cH:3][cH:4][cH:5][cH:6][cH:7]1)[n:8]1[cH:9][c:10]([CH:17]=[CH:18][CH:19]=[CH:20][CH:21]=[O:22])[c:11]2[cH:12][cH:13][cH:14][cH:15][c:16]12

Participants

7

Reactant 6

HCID 3283Diethyl EtherHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 166653Hydride4×HCID 54565894Ethyl 5-(1-benzylindol-3yl)-2,4-pentadienoate

Product 1

HCID 541315495-(1-Benzylindol-3-yl)-2,4-pentadienal

Sources & evidence

ORD record
ord-3c76ef10964446c69bd98477bf10f7f0
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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