Dimethyl Sulfide → Methyl 3-bromo-5-(hydroxymethyl)benzoate

HRID 826482Notes

Reaction equation

HRID 826482 reaction equation

[BH3:18].[Br:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][c:9]([C:11](=[O:12])[O:13][CH3:14])[cH:10]1.[CH3:15][S:16][CH3:17].[O:19]1[CH2:20][CH2:21][CH2:22][CH2:23]1>>[Br:1][c:2]1[cH:3][c:4]([CH2:5][OH:6])[cH:8][c:9]([C:11](=[O:12])[O:13][CH3:14])[cH:10]1

Participants

5

Reactant 4

HCID 1068Dimethyl Sulfide

HCID 6331Borane

HCID 8028Tetrahydrofuran

HCID 225936413-Bromo-5-(methoxycarbonyl)benzoic acid

Product 1

HCID 11356988Methyl 3-bromo-5-(hydroxymethyl)benzoate

Sources & evidence

ORD record: ord-f96747ef99454a77a0bdd09576ef45dd
Source dataset: Test data from https://doi.org/10.1039/C8SC04228D
DOI: 10.1039/C8SC04228D

Reaction notes

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