Dimethylformamide → 4H-Benzo[b]imidazo[1,2-d][1,4]oxazine-7-carbaldehyde

HRID 826770Notes

Reaction equation

HRID 826770 reaction equation
[C:17](=[O:18])([O-:19])[O-:20].[CH3:23][NH:24][CH:25]1[CH2:26][CH2:27][CH2:28][CH2:29][CH:30]1[NH:31][CH3:32].[Cs+:21].[Cs+:22].[Cu:33][I:34].[O:35]=[CH:36][N:37]([CH3:38])[CH3:39].[nH:1]1[c:2]([CH2:6][O:7][c:8]2[cH:9][c:10]([CH:11]=[O:12])[cH:13][cH:14][c:15]2[I:16])[n:3][cH:4][cH:5]1>>[n:1]1[c:2]2[n:3]([cH:4][cH:5]1)-[c:15]1[c:8]([cH:9][c:10]([CH:11]=[O:12])[cH:13][cH:14]1)[O:7][CH2:6]2

Participants

7

Reactant 6

HCID 6228DimethylformamideHCID 19660Carbonate IonHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 104967Cesium cation2×HCID 5510741-N,2-N-dimethylcyclohexane-1,2-diamineHCID 866614633-(1H-imidazol-2-ylmethoxy)-4-iodobenzaldehyde

Product 1

HCID 866614644H-Benzo[b]imidazo[1,2-d][1,4]oxazine-7-carbaldehyde

Sources & evidence

ORD record
ord-a1086366928645aa8b7111f511a10012
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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