Dimethylformamide → 3-(2-Cyanophenyl)-5-(2-pyridinecarbonyl)-1-phenyl-1,2-dihydropyridin-2-one

HRID 826775Notes

Reaction equation

HRID 826775 reaction equation
[C:23](#[N:24])[c:25]1[c:26]([B:31]2[O:32][CH:33]([C:34]([O-:35])=[O:36])[CH:37]=[CH:38][O:39]2)[cH:27][cH:28][cH:29][cH:30]1.[C:40](=[O:41])([O-:42])[O-:43].[CH3:46][N:47]([CH3:48])[CH:49]=[O:50].[CH3:51][CH2:52][O:53][C:54](=[O:55])[CH3:56].[Cs+:44].[Cs+:45].[n:1]1[c:2]([C:7](=[O:8])[c:9]2[cH:10][c:11]([Br:22])[c:12](=[O:21])[n:13](-[c:15]3[cH:16][cH:17][cH:18][cH:19][cH:20]3)[cH:14]2)[cH:3][cH:4][cH:5][cH:6]1>>[n:1]1[c:2]([C:7](=[O:8])[c:9]2[cH:10][c:11](-[c:26]3[c:25]([C:23]#[N:24])[cH:30][cH:29][cH:28][cH:27]3)[c:12](=[O:21])[n:13](-[c:15]3[cH:16][cH:17][cH:18][cH:19][cH:20]3)[cH:14]2)[cH:3][cH:4][cH:5][cH:6]1

Participants

7

Reactant 6

HCID 6228DimethylformamideHCID 8857Ethyl AcetateHCID 19660Carbonate IonHCID 104967Cesium cation2×HCID 223189285-(2-Pyridinecarbonyl)-1-phenyl-3-bromo-1,2-dihydropyridin-2-oneHCID 865903732-(2-Cyanophenyl)-1,3,2-dioxaborinate

Product 1

HCID 223190923-(2-Cyanophenyl)-5-(2-pyridinecarbonyl)-1-phenyl-1,2-dihydropyridin-2-one

Sources & evidence

ORD record
ord-9ae1017bae0a4021abdb3fd089390b17
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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