Triethylamine → Ethyl 4-[2-(5,5-dimethyl-8-oxo-6,7-dihydronaphthalen-2-yl)ethenyl]benzoate

HRID 834922Notes

Reaction equation

HRID 834922 reaction equation
[CH3:1][C:2]1([CH3:14])[CH2:3][CH2:4][C:5](=[O:13])[c:6]2[cH:7][c:8]([Br:12])[cH:9][cH:10][c:11]21.[CH3:28][c:29]1[cH:30][cH:31][cH:32][cH:33][c:34]1[P:35]([c:36]1[cH:37][cH:38][cH:39][cH:40][c:41]1[CH3:42])[c:43]1[cH:44][cH:45][cH:46][cH:47][c:48]1[CH3:49].[CH3:50][CH2:51][N:52]([CH2:53][CH3:54])[CH2:55][CH3:56].[CH:15](=[CH2:16])[c:17]1[cH:18][cH:19][c:20]([C:21](=[O:22])[O:23][CH2:24][CH3:25])[cH:26][cH:27]1>>[CH3:1][C:2]1([CH3:14])[CH2:3][CH2:4][C:5](=[O:13])[c:6]2[cH:7][c:8]([CH:16]=[CH:15][c:17]3[cH:18][cH:19][c:20]([C:21](=[O:22])[O:23][CH2:24][CH3:25])[cH:26][cH:27]3)[cH:9][cH:10][c:11]21

Participants

5

Reactant 4

HCID 8471TriethylamineHCID 80271Tri-o-tolylphosphineHCID 107533577-Bromo-4,4-dimethyl-1,2,3,4-tetrahydronaphthalen-1-oneHCID 10866858Ethyl 4-vinylbenzoate

Product 1

HCID 54178515Ethyl 4-[2-(5,5-dimethyl-8-oxo-6,7-dihydronaphthalen-2-yl)ethenyl]benzoate

Sources & evidence

ORD record
ord-a205d5068b7d4fdaa045c7de188a06e6
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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