Dimethyl Sulfide → 3-Hydroxy-4-methylbenzaldehyde

HRID 836034Notes

Reaction equation

HRID 836034 reaction equation
[BH3:15].[CH2:37]1[O:38][CH2:39][CH2:40][CH2:41]1.[CH3:12][S:13][CH3:14].[Cr:16]([O:17][Cr:18]([O-:19])(=[O:20])=[O:21])([O-:22])(=[O:23])=[O:24].[OH:1][c:2]1[cH:3][c:4]([C:5](=[O:6])[OH:7])[cH:8][cH:9][c:10]1[CH3:11].[nH+:25]1[cH:26][cH:27][cH:28][cH:29][cH:30]1.[nH+:31]1[cH:32][cH:33][cH:34][cH:35][cH:36]1>>[OH:1][c:2]1[cH:3][c:4]([CH:5]=[O:6])[cH:8][cH:9][c:10]1[CH3:11]

Participants

7

Reactant 6

HCID 1068Dimethyl SulfideHCID 6331BoraneHCID 8028TetrahydrofuranHCID 24503Dichromate ionHCID 685123-Hydroxy-4-methylbenzoic acidHCID 4989215Pyridinium2×

Product 1

HCID 5851823-Hydroxy-4-methylbenzaldehyde

Sources & evidence

ORD record
ord-971a2f9a8fd944bcaf377803a4cac465
Source dataset
Test data from https://doi.org/10.1039/C8SC04228D

Reaction notes

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