Carbon Dioxide → HCID 86735764, compound

HRID 839483Notes

Reaction equation

HRID 839483 reaction equation
[NH2:1][NH:2][C:3]([NH:5][NH2:6])=[O:4].C(=O)(O)[O-].[Na+].[CH2:12]([S:16](Cl)(=[O:18])=[O:17])[CH2:13][CH2:14][CH3:15].C(=O)=O>O.CO>[CH2:12]([S:16]([NH:1][NH:2][C:3]([NH:5][NH:6][S:16]([CH2:12][CH2:13][CH2:14][CH3:15])(=[O:18])=[O:17])=[O:4])(=[O:18])=[O:17])[CH2:13][CH2:14][CH3:15]

Participants

7

Reactant 4

HCID 280Carbon DioxideHCID 73948CarbohydrazideHCID 754301-Butanesulfonyl chlorideHCID 516892Sodium Bicarbonate

Product 1

HCID 86735764HCID 86735764, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 962WaterSolvent

Procedure

A mixture of 11.25 g (0.125 mole) carbohydrazide, 25 g sodium bicarbonate, 200 ml methanol and 37 g (0.25 mole) 1-butanesulfonyl chloride was heated to 60° C until evolution of CO2 ceased. The mix was cooled and water was added to precipitate the product. The initial precipitate weighed 12 g (dry). This melted with decomposition at 195°-197° C.

Workup

  1. temperatureThe mix was cooled
  2. customto precipitate the product
  3. custom12 g (dry)
  4. customThis melted with decomposition at 195°-197° C.

Sources & evidence

ORD record
ord-1d2326a3e8174222bf77a5207ca102b0
Source dataset
uspto-grants-1978_06
Patent number
US04096100

Reaction notes

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