Dodecylamine → dodecylsulfam

HRID 843567Notes

Reaction equation

HRID 843567 reaction equation
[CH2:1]([NH2:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].Cl[S:15]([OH:18])(=[O:17])=[O:16]>N1C=CC=CC=1>[CH2:1]([NH:13][S:15](=[O:17])(=[O:16])[OH:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 13583DodecylamineHCID 24638Chlorosulfonic acid

Product 1

HCID 204302dodecylsulfam

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Dodecyl amine (0.1 mol) is added to a round bottom flask equipped with magnetic stirrer and dissolved in anhydrous pyridine. Next, chlorosulfonic acid (0.1 mol) is added dropwise with stirring to the chilled solution. The resulting product, dodecyl sulfamic acid, is then collected by filtration, washed with water and dried in an oven.

Workup

  1. customequipped with magnetic stirrer
  2. filtrationThe resulting product, dodecyl sulfamic acid, is then collected by filtration
  3. washwashed with water
  4. customdried in an oven

Sources & evidence

ORD record
ord-a4506359bda14e6486864383343f1663
Source dataset
uspto-grants-2002_04
Patent number
US06380182B1

Reaction notes

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