m-Chloroperbenzoic acid → HCID 14157411, compound

HRID 845338Notes

Reaction equation

HRID 845338 reaction equation
[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH:11]([CH3:13])[CH3:12])[CH:9]=[CH2:10])=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:22])C=1>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[CH:6][C:5]([CH:8]([CH:9]2[CH2:10][O:22]2)[CH:11]([CH3:13])[CH3:12])=[CH:4][CH:3]=1

Participants

4

Reactant 2

HCID 70297m-Chloroperbenzoic acidHCID 136165471-Chloro-4-(4-methylpent-1-en-3-yl)benzene

Product 1

HCID 14157411HCID 14157411, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

A mixture of 4 g of the product of Example 1 and 4.5 g of m-chloroperbenzoic acid in 50 mL of chloroform was stirred overnight at room temperature and filtered. The filtrate was washed with aqueous NaHSO3, aqueous NaHCO3, brine, dried (Na2SO4), and concentrated. The residue was a mixture of diastereomeric epoxides.

Workup

  1. filtrationfiltered
  2. washThe filtrate was washed with aqueous NaHSO3, aqueous NaHCO3, brine
  3. dry with materialdried (Na2SO4)
  4. concentrationconcentrated
  5. additiona mixture of diastereomeric epoxides

Sources & evidence

ORD record
ord-3820bf2cf01a4547b708180a0fa88169
Source dataset
uspto-grants-1988_07
Patent number
US04758262

Reaction notes

Loading…