Pentane → HCID 136342795, compound

HRID 845455Notes

Reaction equation

HRID 845455 reaction equation
[OH:1][C:2]1[CH:7]=[CH:6][C:5]([C:8]2[N:12]=[C:11]([S:13]([NH2:16])(=[O:15])=[O:14])[S:10][N:9]=2)=[CH:4][CH:3]=1.C[C:18](C)(C)[C:19]([O-:22])([O-])[O-].[CH3:25]CCCC>>[CH3:25][O:22][C:19](=[N:16][S:13]([C:11]1[S:10][N:9]=[C:8]([C:5]2[CH:6]=[CH:7][C:2]([OH:1])=[CH:3][CH:4]=2)[N:12]=1)(=[O:15])=[O:14])[CH3:18]

Participants

4

Reactant 3

HCID 8003PentaneHCID 21927715TrimethylorthoacetateHCID 135603722HCID 135603722, compound

Product 1

HCID 136342795HCID 136342795, compound

Procedure

A mixture of 3.0 g of 3-(4-hydroxyphenyl)-1,2,4-thiadiazole-5-sulfonamide and 20 ml of trimethylorthoacetate was stirred at room temperature for 42 hours. Pentane (25 ml) was added and stirring continued overnight. The precipitated solid was triturated with benzene and collected to give 2.4 g of powder, m.p. 190°-192°.

Workup

  1. stirringstirring continued overnight
  2. customThe precipitated solid was triturated with benzene
  3. customcollected

Sources & evidence

ORD record
ord-bcaef99a04f14710ab321dd85423008e
Source dataset
uspto-grants-1988_07
Patent number
US04758578

Reaction notes

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