Azidotrimethylsilane → HCID 136041366, compound

HRID 846499Notes

Reaction equation

HRID 846499 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([CH3:9])=[CH:4][C:3]=1[N:10]=[C:11]=[O:12].C[Si]([N:17]=[N+:18]=[N-:19])(C)C>>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[C:5]([CH3:9])=[CH:4][C:3]=1[N:10]1[C:11](=[O:12])[NH:19][N:18]=[N:17]1

Participants

3

Reactant 2

HCID 78378AzidotrimethylsilaneHCID 19882834HCID 19882834, compound

Product 1

HCID 136041366HCID 136041366, compoundYield 27.3%

Procedure

In the manner of Example 1, Step A, the reaction of 3.4 g (0.016 mole) of 2,4-dichloro-5-methylphenyl isocyanate and 3.6 g (0.031 mole) of trimethylsilyl azide produced 1.07 g of 1-(2,4-dichloro-5-methylphenyl)-1,4-dihydro-5H-tetrazol-5-one as a solid, mp 135°-137° C.

Sources & evidence

ORD record
ord-a799c848cea942e9b52542c03f4e06bf
Source dataset
uspto-grants-1992_08
Patent number
US05136868

Reaction notes

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