1-Oxo-1,2,3,4-tetrahydrophenanthrene → HCID 348924, compound

HRID 847233Notes

Reaction equation

HRID 847233 reaction equation
[C:1]1(=O)[C:14]2[CH:13]=[CH:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH2:4][CH2:3][CH2:2]1.Cl.[NH2:17][OH:18]>N1C=CC=CC=1>[C:1]1(=[N:17][OH:18])[C:14]2[CH:13]=[CH:12][C:11]3[C:6](=[CH:7][CH:8]=[CH:9][CH:10]=3)[C:5]=2[CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 2256831-Oxo-1,2,3,4-tetrahydrophenanthreneHCID 443297Hydroxyamine hydrochloride

Product 1

HCID 348924HCID 348924, compound

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

To a solution of 1,2,3,4-tetrahydrophenanthren-1-one (1.0 g, 5.1 mmol) in pyridine was added hydroxylamine hydrochloride (0.69 g, 10.0 mmol). The resulting mixture was stirred at room temperature overnight. The solvent was removed in vacuo. Water was added to the residue, which was then filtered and dried to provide the oxime.

Workup

  1. customThe solvent was removed in vacuo
  2. additionWater was added to the residue, which
  3. filtrationwas then filtered
  4. customdried

Sources & evidence

ORD record
ord-6dd41acd27f74da6b65e046fbddafbf7
Source dataset
uspto-grants-1992_08
Patent number
US05140047

Reaction notes

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