Chlorotrimethylsilane → (Cyclohexyloxy)trimethylsilane

HRID 847481Notes

Reaction equation

HRID 847481 reaction equation
[CH:1]1([OH:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[CH3:8][Si:9]([CH3:12])([CH3:11])Cl>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC>[CH3:8][Si:9]([CH3:12])([CH3:11])[O:7][CH:1]1[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1

Participants

4

Reactant 2

HCID 6397ChlorotrimethylsilaneHCID 7966Cyclohexanol

Product 1

HCID 262864(Cyclohexyloxy)trimethylsilane

Reagents, catalysts & solvents 1

HCID 74236Tetrabutylammonium BromideCatalyst

Procedure

1 mole of cyclohexanol, 1.5 moles of trimethylchorosilane and 0.0005 moles of tetra-n-butyl ammonium bromide were reacted at the reflux temperature (54°-97° C.) as in Example 1 and then worked up by distillation.

Workup

  1. distillationworked up by distillation

Sources & evidence

ORD record
ord-b2a40950a53b4bc1828648cbee2a62b4
Source dataset
uspto-grants-1992_08
Patent number
US05142081

Reaction notes

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