Ethyl Acetate → HCID 23217743, compound

HRID 863379Notes

Reaction equation

[C:1]([C:5]1[CH:6]=[C:7]([C:15]([CH3:25])=[CH:16][CH:17]=[CH:18][C:19]([CH3:24])=[CH:20][C:21]([O-:23])=[O:22])[CH:8]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:10]=1)([CH3:4])([CH3:3])[CH3:2].[CH3:26][CH2:27]OC(C)=O>>[C:1]([C:5]1[CH:6]=[C:7]([CH:15]([CH3:25])[CH2:16]/[CH:17]=[CH:18]/[C:19](/[CH3:24])=[CH:20]/[C:21]([O:23][CH2:26][CH3:27])=[O:22])[CH:8]=[C:9]([C:11]([CH3:12])([CH3:13])[CH3:14])[CH:10]=1)([CH3:2])([CH3:3])[CH3:4]

Participants

Reactant 2

HCID 8857Ethyl Acetate

HCID 86752136HCID 86752136, compound

Product 1

HCID 23217743HCID 23217743, compound

Procedure

Compound 13 was prepared from 12 in a similar manner as described for compound 7: TLC (5% EtOAc-95% hexanes) Rf 0.88; 1H-NMR (CDCl3) δ1.30 (m, 6H, CH2CH3 +CH3), 1.34 (s, 18H, 6(CH3)), 2.20, (s, 3H, CH3), 2.40 (m, 2H, CH2), 2.85 (m, 1H, CH), 4.14 (m, 2H, CH2CH3), 5.62 (s, 1H, =CH), 6.03 (m, 2H, =CH), 7.00 (d, J=I Hz, 2H, Ar-H), 7.24 (t, J=1 Hz, 1H, Ar-H).

Sources & evidence

ORD record: ord-01d69beccb90482ea57a822733737809
Source dataset: uspto-grants-1998_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05721103

Reaction notes

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