2-Methylbenzaldehyde → HCID 54566374, compound

HRID 864417Notes

Reaction equation

HRID 864417 reaction equation
[C:1]1([CH3:9])[C:2]([CH:7]=O)=[CH:3][CH:4]=[CH:5][CH:6]=1.[N:10]([CH2:13][C:14]([O:16][CH3:17])=[O:15])=[N+:11]=[N-:12]>>[CH3:9][C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[CH:7]=[C:13]([N:10]=[N+:11]=[N-:12])[C:14]([O:16][CH3:17])=[O:15]

Participants

3

Reactant 2

HCID 107222-MethylbenzaldehydeHCID 4020482Methyl 2-azidoacetate

Product 1

HCID 54566374HCID 54566374, compound

Procedure

Following the general procedure of PREPARATION 61 and making non-critical variations but starting with o-tolualdehyde (5.0 g), methyl azidoacetate (19.2 g), the title compound is obtained, NMR (300 MHz, CDCl3) 7.96, 7.26-7.18, 7.13, 3.92 and 2.36 δ.

Workup

  1. customthe general procedure of PREPARATION 61

Sources & evidence

ORD record
ord-587d8cd61640432aa20ee216a47548e2
Source dataset
uspto-grants-1996_10
Patent number
US05563142

Reaction notes

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