Phosphorus oxide (P4O10) → Stannic chloride pentahydrate

HRID 864884Notes

Reaction equation

HRID 864884 reaction equation
[O:1]=P12OP3(OP(OP(O3)(O1)=O)(=O)O2)=O.[Cl:15][Sn:16]([Cl:19])([Cl:18])[Cl:17]>O.Cl>[Sn:16]([Cl:19])([Cl:18])([Cl:17])[Cl:15].[OH2:1].[OH2:1].[OH2:1].[OH2:1].[OH2:1]

Participants

5

Reactant 2

HCID 14812Phosphorus oxide (P4O10)2×HCID 24287Tin tetrachloride2×

Product 1

HCID 61442Stannic chloride pentahydrate

Reagents, catalysts & solvents 2

HCID 313Hydrochloric AcidSolvent3×HCID 962WaterSolvent2×

Procedure

Approximately 2000 ml of distilled water was heated to about 80 degrees C. A solution of SnCl4.5H2O in 500 ml of distilled water, 0.445 g SnO2 /ml was prepared. Approximately 7.5 g of P2O5 was dissolved in 63 ml of concentrated HCl, then an additional 31 ml of HCl was added. About 125 ml of concentrated HCl was added to the SnCl4 solution. The SnCl4 and P2O5 solutions were mixed together in a beaker.

Sources & evidence

ORD record
ord-3161fa20926c433aac06d75428ad2a59
Source dataset
uspto-grants-1996_10
Patent number
US05565144

Reaction notes

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