Dichloromethane → HCID 23374674, compound

HRID 865786Notes

Reaction equation

HRID 865786 reaction equation
C([O:5][CH2:6][CH:7]([O:16][CH2:17][CH2:18][O:19][CH:20]([CH3:22])[CH3:21])[CH2:8][O:9][CH2:10][CH2:11][O:12][CH:13]([CH3:15])[CH3:14])(C)(C)C.ClCCl.C(=O)([O-])[O-].[K+].[K+]>C(OCC)C>[CH:20]([O:19][CH2:18][CH2:17][O:16][CH:7]([CH2:8][O:9][CH2:10][CH2:11][O:12][CH:13]([CH3:15])[CH3:14])[CH2:6][OH:5])([CH3:22])[CH3:21]

Participants

5

Reactant 3

HCID 6344DichloromethaneHCID 11430Potassium CarbonateHCID 23374675HCID 23374675, compound

Product 1

HCID 23374674HCID 23374674, compound

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

Compound 32 was prepared as described for 29. The reagents used were as follows, compound 26 (g, mol.), tetrafluoroboric acid-diethyl ether complex ml of a 54% solution in diethyl ether), dichloromethane (100 ml) and excess potassium carbonate. the final yield was a colorless liquid (g, %), (bpt. °C., torr.): 1H-NMR (CDCl3), d, (ppm). Mass spectroscopy, m/e M+.

Workup

  1. customthe final yield

Sources & evidence

ORD record
ord-112eb504eeea4e7aad7fc841b748465b
Source dataset
uspto-grants-1996_10
Patent number
US05567783

Reaction notes

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