Water → N-Allyl-4,6-dichloro-1,3,5-triazin-2-amine

HRID 866474Notes

Reaction equation

HRID 866474 reaction equation
[N:1]1[C:8]([Cl:9])=[N:7][C:5]([Cl:6])=[N:4][C:2]=1Cl.O.[CH2:11]([NH2:14])[CH:12]=[CH2:13].C(=O)([O-])[O-].[Na+].[Na+]>CC(C)=O>[CH2:11]([NH:14][C:2]1[N:1]=[C:8]([Cl:9])[N:7]=[C:5]([Cl:6])[N:4]=1)[CH:12]=[CH2:13]

Participants

6

Reactant 4

HCID 962WaterHCID 7853AllylamineHCID 7954Cyanuric chlorideHCID 10340Sodium Carbonate

Product 1

HCID 35294N-Allyl-4,6-dichloro-1,3,5-triazin-2-amine

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

18.5 parts of cyanuric chloride were dissolved in 100 parts of acetone and added, while stirring, to a mixture of 300 parts of water and 400 parts of crushed ice. The suspension thus obtained was added to 5.7 parts of allylamine over a period of 30 minutes and subsequently to an aqueous solution of 5.3 parts of sodium carbonate. The white crystalline reaction product was suction-filtered, washed several times with iced water, and dried over phosphorus pentoxide.

Workup

  1. additionadded
  2. customThe suspension thus obtained
  3. filtrationThe white crystalline reaction product was suction-filtered
  4. washwashed several times with iced water
  5. dry with materialdried over phosphorus pentoxide

Sources & evidence

ORD record
ord-6dc3f7089bf74ba99d417481d4d27e57
Source dataset
uspto-grants-1978_07
Patent number
US04098985

Reaction notes

Loading…