tert-Butyl hydroperoxide → HCID 20318133, compound

HRID 866724Notes

Reaction equation

HRID 866724 reaction equation
[C:1](N=NC(Cl)(C)C)(C)(C)[CH3:2].[K].C(OO)(C)(C)C.[C:18]([N:22]=[N:23][C:24]([O:27][O:28][C:29]([CH3:32])(C)C)([CH3:26])[CH3:25])([CH3:21])([CH3:20])[CH3:19].C(N=NC(O)(C)C)(C)(C)C>>[C:18]([N:22]=[N:23][C:24]([O:27][O:28][CH2:29][CH2:32][CH2:1][CH3:2])([CH3:25])[CH3:26])([CH3:19])([CH3:20])[CH3:21]

Participants

6

Reactant 5

HCID 6410tert-Butyl hydroperoxideHCID 945822-Propanol, 2-[(1,1-dimethylethyl)azo]-HCID 5462222PotassiumHCID 1564434955296-56-5HCID 20393238HCID 20393238, compound

Product 1

HCID 20318133HCID 20318133, compound

Procedure

Crude 2-t-butylazo-2-butylperoxypropane was prepared by reacting 2-t-butylazo-2-chloropropane with an aqueous solution of the potassium salt of t-butyl hydroperoxide according to the method described in MacLeay, Lange and Sheppard application Ser. No. 426,411 filed Dec. 19, 1973, (which is incorporated herein by reference). The resultant product contained approximately 75% 2-t-butylazo -2-t-butylperoxypropane and 25% 2-t-butylazo-2-hydroxy-propane (which has been marketed as "LUCEL 3").

Sources & evidence

ORD record
ord-febbb632064a424f962542299057cc68
Source dataset
uspto-grants-1978_07
Patent number
US04101464

Reaction notes

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