Oxygen → Allyl methacrylate

HRID 867594Notes

Reaction equation

HRID 867594 reaction equation
C(N1CCCC1=O)=C.[C:9]([O:14][CH2:15][CH2:16][CH2:17]CCCCCCCCC)(=[O:13])[C:10]([CH3:12])=[CH2:11].O=O.N(C(C)(C)C#N)=NC(C)(C)C#N>O>[C:9]([O:14][CH2:15][CH:16]=[CH2:17])(=[O:13])[C:10]([CH3:12])=[CH2:11]

Participants

7

Reactant 5

HCID 977OxygenHCID 6547AzobisisobutyronitrileHCID 6917N-vinyl-2-pyrrolidoneHCID 8906Lauryl MethacrylateHCID 178435178HCID 178435178, compound

Product 1

HCID 7274Allyl methacrylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Procedure

The dimer of allyl methacrylate, which was prepared according to Example 1, was added in the amount of 1 wt.-% (related to the entire mixture) to the mixture containing 70 wt.-% N-vinylpyrrolidone and 30 wt.-% dodecyl methacrylate. The mixture was homogenized, freed of air oxygen and polymerized in the presence of 0.4 wt.-% azobisisobutyronitrile in a polypropylene mold at 60° C. for 16 h. The resulting gel contained, after swelling with water, 77 wt.-% water at G=0.067 MPa.

Workup

  1. additionwas added in the amount of 1 wt.-% (

Sources & evidence

ORD record
ord-679b2760a4624fda878fb25f59969bf6
Source dataset
uspto-grants-1988_10
Patent number
US04775731

Reaction notes

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