Water → HCID 22133497, compound

HRID 867846Notes

Reaction equation

HRID 867846 reaction equation
[C:1](=[O:6])([O:4]C)[O:2]C.[CH2:7]([N:11]([CH2:16][CH2:17][CH2:18][CH3:19])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:8][CH2:9][CH3:10].O>CO>[C:1](=[O:2])([O-:6])[OH:4].[CH2:16]([NH+:11]([CH2:7][CH2:8][CH2:9][CH3:10])[CH2:12][CH2:13][CH2:14][CH3:15])[CH2:17][CH2:18][CH3:19]

Participants

5

Reactant 3

HCID 962WaterHCID 7622TributylamineHCID 12021Dimethyl Carbonate

Product 1

HCID 22133497HCID 22133497, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

30.2 g of dimethyl carbonate, 62.1 g of tri-n-butylamine, 30.5 g of water and 15.0 g of methanol were introduced in the same reactor as used in Preparation Example 1 and heated with stirring. After the temperature in the reactor reached 140° C., the reaction was continued for 7 hours at 140° C. Tributylammonium hydrogencarbonate was obtained in a yield of 84.3 mol % (based on tri-n-butylamine).

Workup

  1. customas used in Preparation Example 1
  2. temperatureheated
  3. customreached 140° C.

Sources & evidence

ORD record
ord-9002d474b4894143ac39deb1821c46e7
Source dataset
uspto-grants-1988_10
Patent number
US04776929

Reaction notes

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