HRID87242

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID259

Bromide

Br-

HCID813

Potassium cation

K+

HCID947

Nitrogen

HCID8028

Tetrahydrofuran

C4H8O

HCID2733423

(Bromomethyl)triphenylphosphonium bromide

C19H17BrP+

HCID4574913

未命名化合物

HCID22219270

未命名化合物

PRODUCTS

产物

HCID91243793

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD记录: ord-2c3bf5f45c1c4e8a8a11e6060763c551
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (2/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (2/10)

反应SMILES

[Br-:7].[Br:8][CH2:9][P+:10]([c:11]1[cH:12][cH:13][cH:14][cH:15][cH:16]1)([c:17]1[cH:18][cH:19][cH:20][cH:21][cH:22]1)[c:23]1[cH:24][cH:25][cH:26][cH:27][cH:28]1.[CH3:1][C:2]([CH3:3])([O-:4])[CH3:5].[CH:29]1([NH:34][c:35]2[c:36]3[n:37][cH:38][n:39]([CH:44]4[O:45][CH:46]([CH2:54][CH:55]=[O:56])[CH:47]5[O:48][C:49]([CH3:52])([CH3:53])[O:50][CH:51]45)[c:40]3[n:41][cH:42][n:43]2)[CH2:30][CH2:31][CH2:32][CH2:33]1.[K+:6].[N:57]#[N:58].[O:59]1[CH2:60][CH2:61][CH2:62][CH2:63]1>>[Br:8][CH:9]=[CH:55][CH2:54][CH:46]1[O:45][CH:44]([n:39]2[cH:38][n:37][c:36]3[c:35]([NH:34][CH:29]4[CH2:30][CH2:31][CH2:32][CH2:33]4)[n:43][cH:42][n:41][c:40]32)[CH:51]2[CH:47]1[O:48][C:49]([CH3:52])([CH3:53])[O:50]2