Ethanol → HCID 59412614, compound

HRID 877301Notes

Reaction equation

HRID 877301 reaction equation
[Br:1]N1C(=O)CCC1=O.[C:9]1([C:15]2[C:16]3[C:21]([C:22]([C:29]4[C:34]5=[CH:35][CH:36]=[C:37]6[C:46]([CH:45]=[C:44]7[C:39]([CH:40]=[CH:41][CH:42]=[CH:43]7)=[CH:38]6)=[C:33]5[CH:32]=[CH:31][CH:30]=4)=[C:23]4[C:28]=2[CH:27]=[CH:26][CH:25]=[CH:24]4)=[CH:20][CH:19]=[CH:18][CH:17]=3)[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1.C(O)C>CN(C=O)C>[Br:1][C:38]1[C:37]2[C:46]([CH:45]=[C:44]3[C:39]=1[CH:40]=[CH:41][CH:42]=[CH:43]3)=[C:33]1[CH:32]=[CH:31][CH:30]=[C:29]([C:22]3[C:21]4[C:16](=[CH:17][CH:18]=[CH:19][CH:20]=4)[C:15]([C:9]4[CH:10]=[CH:11][CH:12]=[CH:13][CH:14]=4)=[C:28]4[C:23]=3[CH:24]=[CH:25][CH:26]=[CH:27]4)[C:34]1=[CH:35][CH:36]=2

Participants

5

Reactant 3

HCID 702EthanolHCID 67184N-bromobutanimideHCID 59412708HCID 59412708, compound

Product 1

HCID 59412614HCID 59412614, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

20 g (116 mmol) of N-bromosuccinimide are added at 100° C. to a suspension of 55 g (116 mmol) of 4-(9-phenylanthracen-10-yl)benz[a]anthracene in 500 ml of DMF. After 3 h, 500 ml of ethanol are added at room temperature, and the solid is filtered off with suction, washed with ethanol and dried. Yield: 63 g (113 mmol), 65%.

Workup

  1. filtrationthe solid is filtered off with suction
  2. washwashed with ethanol
  3. customdried

Sources & evidence

ORD record
ord-b0540b763a384e68866a90a40eecf424
Source dataset
uspto-grants-2015_03
Patent number
US08986852B2

Reaction notes

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