Dichloromethane → (2-Bromomethylbenzyloxy)-t-butyldiphenylsilane

HRID 88572Notes

Reaction equation

HRID 88572 reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][c:8]1[c:9]([CH2:14][OH:15])[cH:10][cH:11][cH:12][cH:13]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)[c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1.[C:28]([Br:29])([Br:30])([Br:31])[Br:32].[CH3:52][CH2:53][O:54][C:55](=[O:56])[CH3:57].[Cl:58][CH2:59][Cl:60].[c:33]1([P:34]([c:35]2[cH:36][cH:37][cH:38][cH:39][cH:40]2)[c:41]2[cH:42][cH:43][cH:44][cH:45][cH:46]2)[cH:47][cH:48][cH:49][cH:50][cH:51]1>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([O:6][CH2:7][c:8]1[c:9]([CH2:14][Br:29])[cH:10][cH:11][cH:12][cH:13]1)([c:16]1[cH:17][cH:18][cH:19][cH:20][cH:21]1)[c:22]1[cH:23][cH:24][cH:25][cH:26][cH:27]1

Participants

6

Reactant 5

HCID 6344DichloromethaneHCID 8857Ethyl AcetateHCID 11205Carbon tetrabromideHCID 11776TriphenylphosphineHCID 11440297[2-[(t-Butyldiphenylsilyloxy)methyl]phenyl]methanol

Product 1

HCID 59750893(2-Bromomethylbenzyloxy)-t-butyldiphenylsilane

Sources & evidence

ORD record
ord-42ece8b460cd4517bbb8450b749f94fd
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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