Hydrogen Peroxide → HCID 86745889, compound

HRID 892735Notes

Reaction equation

HRID 892735 reaction equation
[OH:1]O.[ClH:3].[CH3:4][C:5]1([CH3:17])[N:10]([N+:11]2[N-:12][O:13][C:14](=[NH:16])[CH:15]=2)[CH2:9][CH2:8][S:7][CH2:6]1>>[ClH:3].[CH3:4][C:5]1([CH3:17])[N:10]([N+:11]2[N-:12][O:13][C:14](=[NH:16])[CH:15]=2)[CH2:9][CH2:8][S:7](=[O:1])[CH2:6]1

Participants

3

Reactant 2

HCID 784Hydrogen PeroxideHCID 86745890HCID 86745890, compound

Product 1

HCID 86745889HCID 86745889, compound

Procedure

1.2 g of a 35% strength aqueous hydrogen peroxide solution are added to a solution of 3 g of 3-(3,3-dimethyl-perhydro-1,4-thiazin-4-yl)-sydnone imine hydrochloride (step g of Example 14) at room temperature with stirring, whereupon the temperature rises somewhat. The mixture is stirred for 2 hours and then concentrated in a water jet vacuum and the residue is recrystallized from ethyl acetate. Yield: 2.5 g; m.p.: 192° C. (dec.).

Workup

  1. stirringThe mixture is stirred for 2 hours
  2. concentrationconcentrated in a water jet vacuum
  3. customthe residue is recrystallized from ethyl acetate

Sources & evidence

ORD record
ord-dc9aad649f8642eeac82bea1d0063938
Source dataset
uspto-grants-1992_06
Patent number
US05120732

Reaction notes

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