Benzyl mercaptan → 4-(Benzylsulfanyl)benzaldehyde

HRID 892830Notes

Reaction equation

HRID 892830 reaction equation
[CH2:1]([SH:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Br[C:10]1[CH:17]=[CH:16][C:13]([CH:14]=[O:15])=[CH:12][CH:11]=1.CCCCCC>C(OCC)(=O)C>[CH2:1]([S:8][C:10]1[CH:17]=[CH:16][C:13]([CH:14]=[O:15])=[CH:12][CH:11]=1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7509Benzyl mercaptanHCID 8058HexaneHCID 707414-Bromobenzaldehyde

Product 1

HCID 128424604-(Benzylsulfanyl)benzaldehyde

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Title product was prepared from benzyl mercaptan (145 mmol, 17.9 g) and 4-bromobenzaldehyde according to the method of Preparation 1 yielding 4 g of purified product following chromatography on silica gel using 9:1 hexane:ethyl acetate as eluant.

Sources & evidence

ORD record
ord-e6841936f9a64ba795b5b07ba3f25e77
Source dataset
uspto-grants-1992_06
Patent number
US05120754

Reaction notes

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