m-Chloroperbenzoic acid → HCID 19782074, compound

HRID 893335Notes

Reaction equation

HRID 893335 reaction equation
[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([CH2:6][CH:7]2[C:13](=[CH2:14])[C:12]([CH3:16])([CH3:15])[CH2:11][CH2:10][CH2:9][CH2:8]2)=[CH:4][CH:3]=1.ClC1C=CC=C(C(OO)=[O:27])C=1.[OH-].[Ca+2].[OH-]>C(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:18]=[CH:17][C:5]([CH2:6][CH:7]2[C:13]3([O:27][CH2:14]3)[C:12]([CH3:15])([CH3:16])[CH2:11][CH2:10][CH2:9][CH2:8]2)=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 70297m-Chloroperbenzoic acidHCID 6093208Calcium HydroxideHCID 19782078HCID 19782078, compound

Product 1

HCID 19782074HCID 19782074, compound

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

In 5 ml of chloroform was dissolved 340 mg of 7-(4-chlorobenzyl)-2,2-dimethyl-1-methylenecycloheptane [Compound (III-3) in Table III], and then 450 mg of m-chloroperbenzoic acid was added to the mixture over 10 minutes and the mixture was stirred at room temperature for one hour. Next, 385 mg of calcium hydroxide was added and the mixture was stirred at room temperature for 10 minutes.

Workup

  1. stirringthe mixture was stirred at room temperature for 10 minutes

Sources & evidence

ORD record
ord-dfa852c929c64b05a4fcdb062b5c8df9
Source dataset
uspto-grants-1992_06
Patent number
US05124345

Reaction notes

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