Sodium Bicarbonate → HCID 13543950, compound

HRID 904671Notes

Reaction equation

HRID 904671 reaction equation
[Br:1][C:2]1[C:11]2[C:6](=[C:7]([CH2:20][CH2:21][CH3:22])[C:8]3[O:15][C:14]([C:16]([OH:18])=[O:17])=[CH:13][C:12](=[O:19])[C:9]=3[CH:10]=2)[N:5]=[C:4]([C:23]([OH:25])=[O:24])[CH:3]=1.C(=O)(O)[O-].[Na+:30]>O>[Br:1][C:2]1[C:11]2[C:6](=[C:7]([CH2:20][CH2:21][CH3:22])[C:8]3[O:15][C:14]([C:16]([O-:18])=[O:17])=[CH:13][C:12](=[O:19])[C:9]=3[CH:10]=2)[N:5]=[C:4]([C:23]([O-:25])=[O:24])[CH:3]=1.[Na+:30].[Na+:30]

Participants

4

Reactant 2

HCID 516892Sodium BicarbonateHCID 13543951HCID 13543951, compound

Product 1

HCID 13543950HCID 13543950, compoundYield 94.9%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

The product of step (c), (2.166 g, 5.22 mmole), was added slowly to a solution of sodium bicarbonate, (0.876 g, 10.44 mmole), in water (35 ml). The resulting solution was filtered and the filtrate was freeze-dried to give the required salt as a brown solid, (2.23 g) 93%. The NMR spectrum was consistent with the required structure.

Workup

  1. filtrationThe resulting solution was filtered
  2. customthe filtrate was freeze-dried

Sources & evidence

ORD record
ord-3214c3d5182a4e82a5ab8fe424a18232
Source dataset
uspto-grants-1983_12
Patent number
US04419352

Reaction notes

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