Butyl Chloride → HCID 57110154, compound

HRID 904987Notes

Reaction equation

HRID 904987 reaction equation
[NH2:1][C:2]1[N:6]=[C:5]([S:7][CH3:8])[N:4]([CH3:9])[N:3]=1.[CH:10]([O:13][C:14]([C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][C:17]=1[S:22]([N:25]=[C:26]=[O:27])(=[O:24])=[O:23])=[O:15])([CH3:12])[CH3:11].ClCCCC>C(Cl)Cl>[CH3:9][N:4]1[C:5]([S:7][CH3:8])=[N:6][C:2]([NH:1][C:26]([NH:25][S:22]([C:17]2[CH:18]=[CH:19][CH:20]=[CH:21][C:16]=2[C:14]([O:13][CH:10]([CH3:12])[CH3:11])=[O:15])(=[O:24])=[O:23])=[O:27])=[N:3]1

Participants

5

Reactant 3

HCID 8005Butyl ChlorideHCID 5228203-Amino-1-methyl-5-methylthio-1,2,4-triazoleHCID 13305294Propan-2-yl 2-[(oxomethylidene)sulfamoyl]benzoate

Product 1

HCID 57110154HCID 57110154, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

A mixture of 0.7 grams (0.00486 mole) of 3-amino-1-methyl-5-methylthio-1H-1,2,4-triazole and 4.0 grams of 2-(isopropoxycarbonyl)benzenesulfonylisocyanate was stirred in 12 ml of dry methylene chloride at ambient temperature overnight. After addition of 4 ml of 1-chlorobutane, a white solid precipitated which was filtered, washed with 1-chlorobutane and dried, yield 1.3 grams, m.p. 192°-194°.

Workup

  1. customa white solid precipitated which
  2. filtrationwas filtered
  3. washwashed with 1-chlorobutane
  4. customdried

Sources & evidence

ORD record
ord-65b1b2576cc641acafd0d2cb4a787528
Source dataset
uspto-grants-1983_12
Patent number
US04421550

Reaction notes

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