HRID9134

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID7501

Styrene

C8H8

HCID8471

Triethylamine

C6H15N

结构：c1ccc(P(CCCP(c2ccccc2)c2ccccc2)c2ccccc2)cc1

HCID81219

Phosphine, 1,3-propanediylbis[diphenyl-

C27H26P2

HCID21985564

未命名化合物

PRODUCTS

生成物

结构：CCNC(=O)Nc1nc2ccc(/C=C/c3ccccc3)cc2s1

HCID21985547

未命名化合物

收率 62%

AUXILIARIES

试剂、催化剂与溶剂

结构：Cl[Pd](Cl)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1

催化剂HCID178418476

未命名化合物

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

A mixture of 1-(6-bromo-2-benzothiazolyl)-3-ethylurea, Pd(PPh3)2Cl2, dppp, triethylamine, styrene, and two crystals of BHT in anhydrous DMF was reacted according to the procedure of Example 225 to give the desired compound 0.201 g (62%). LC/MS 324.2 (M+1); LC retention time 2.87 min.

WORKUP

后处理

customwas reacted