Benzoyl Peroxide → Ethyl-2-Cyanoacrylate Styrene

HRID 917937Notes

Reaction equation

HRID 917937 reaction equation
[C:1]([C:3](=[CH2:9])[C:4]([O:6][CH2:7][CH3:8])=[O:5])#[N:2].[CH2:10]=[CH:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1.C(OOC(=O)C1C=CC=CC=1)(=O)C1C=CC=CC=1>CN(C)C=O>[CH2:7]([O:6][C:4](=[O:5])[C:3]([C:1]#[N:2])=[CH2:9])[CH3:8].[CH2:10]=[CH:11][C:12]1[CH:17]=[CH:16][CH:15]=[CH:14][CH:13]=1

Participants

5

Reactant 3

HCID 7187Benzoyl PeroxideHCID 7501StyreneHCID 81530Ethyl cyanoacrylate

Product 1

HCID 86733663Ethyl-2-Cyanoacrylate Styrene

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Procedure

This copolymer was prepared in a similar manner to that described in Example 1, using 16 g ethyl 2-cyanoacrylate and 4 g styrene, with the only exception that 0.10 gm. benzoyl peroxide was used instead of azobis(isobutyronitrile). The reduced viscosity of this copolymer measured in dimethyl formamide (0.4 g/100 ml.) was 1.23.

Workup

  1. customThis copolymer was prepared in a similar manner to that

Sources & evidence

ORD record
ord-16e9022177504af49dc16eb0fefc9ffe
Source dataset
uspto-grants-1976_07
Patent number
US03968186

Reaction notes

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