Triethylamine → N,N-Diethyl-N-[(3-phenoxyphenyl)methyl]ethanaminium chloride

HRID 918122Notes

Reaction equation

HRID 918122 reaction equation
C1(C)C=CC=CC=1[C:7]1[CH:8]=[C:9]([O:13][C:14]2[CH:19]=[CH:18][CH:17]=[C:16]([C:20]3C=CC=CC=3C)[CH:15]=2)[CH:10]=[CH:11][CH:12]=1.O(C1C=C(C=CC=1)C[Cl:39])C1C=CC=CC=1.[CH2:43]([N:45]([CH2:48][CH3:49])[CH2:46][CH3:47])[CH3:44]>C1C=CC=CC=1>[Cl-:39].[O:13]([C:14]1[CH:15]=[C:16]([CH:17]=[CH:18][CH:19]=1)[CH2:20][N+:45]([CH2:48][CH3:49])([CH2:46][CH3:47])[CH2:43][CH3:44])[C:9]1[CH:8]=[CH:7][CH:12]=[CH:11][CH:10]=1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 932913-Phenoxybenzyl chlorideHCID 70567605HCID 70567605, compound

Product 1

HCID 162156N,N-Diethyl-N-[(3-phenoxyphenyl)methyl]ethanaminium chloride

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

18.2 g of the chlorinated product of m-tolylphenyl ether containing 13.2 g of 3-phenoxybenzyl chloride was treated with a solution of 9.1 g of triethylamine in 60 ml of benzene in the same manner as described in Example 1. Thus, 17.8 g of colorless, needle-like 3-phenoxybenzyl triethyl ammonium chloride was obtained (hygroscopic, no clear m.p.).

Sources & evidence

ORD record
ord-9d9658ba3bf342f2bb42b2a0c40b31c9
Source dataset
uspto-grants-1976_07
Patent number
US03969393

Reaction notes

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