Benzene → N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

HRID 918332Notes

Reaction equation

HRID 918332 reaction equation
Cl[C:2]([CH3:17])([CH3:16])[CH2:3][CH2:4][CH2:5][CH:6]([CH3:15])[CH2:7][CH:8]=[CH:9][C:10]([CH3:14])=[CH:11][CH2:12]Br.BrCC=C(C)C=CCC(C)CCC=C(C)C.C1C=CC=CC=1.[CH2:40]([NH:42][CH2:43][CH3:44])[CH3:41]>C(Cl)Cl>[CH2:40]([N:42]([CH2:12][CH:11]=[C:10]([CH3:14])[CH:9]=[CH:8][CH2:7][CH:6]([CH3:15])[CH2:5][CH2:4][CH:3]=[C:2]([CH3:17])[CH3:16])[CH2:43][CH3:44])[CH3:41]

Participants

6

Reactant 4

HCID 241BenzeneHCID 8021DiethylamineHCID 5387143211-Chloro-3,7,11-trimethyldodeca-2,4-dienyl bromideHCID 54370561HCID 54370561, compound

Product 1

HCID 53837124N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

Five grams of 1 bromo-3,7,11-trimethyldodeca-2,4,10-triene in 25 ml. of benzene is mixed with 4 g. of diethylamine and the mixture stirred for about three hours. Methylene chloride (50 ml.) is added and the mixture washed with dilute sodium hydroxide and then water and evaporated to yield N,N-diethyl 3,7,11-trimethyldodeca-2,4,10-trienylamine.

Workup

  1. washthe mixture washed with dilute sodium hydroxide
  2. customwater and evaporated

Sources & evidence

ORD record
ord-fd1ec86af4c24fd3b2e9cc477e948b13
Source dataset
uspto-grants-1976_07
Patent number
US03970704

Reaction notes

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