Acetate → 3-[3-(6-Phenyl-pyridin-2-ylsulfanyl)-phenyl]-acrylic acid methyl ester

HRID 91998Notes

Reaction equation

HRID 91998 reaction equation
[Br:1][c:2]1[cH:3][c:4]([S:8][c:9]2[n:10][c:11](-[c:15]3[cH:16][cH:17][cH:18][cH:19][cH:20]3)[cH:12][cH:13][cH:14]2)[cH:5][cH:6][cH:7]1.[C:21]([CH:22]=[CH2:23])(=[O:24])[O:25][CH3:26].[CH3:27][CH2:28][N:29]([CH2:30][CH3:31])[CH2:32][CH3:33].[CH3:34][C:35]#[N:36].[O-:38][C:39]([CH3:40])=[O:41].[O-:42][C:43]([CH3:44])=[O:45].[Pd+2:37]>>[c:2]1([CH:23]=[CH:22][C:21](=[O:24])[O:25][CH3:26])[cH:3][c:4]([S:8][c:9]2[n:10][c:11](-[c:15]3[cH:16][cH:17][cH:18][cH:19][cH:20]3)[cH:12][cH:13][cH:14]2)[cH:5][cH:6][cH:7]1

Participants

7

Reactant 6

HCID 175Acetate2×HCID 6342AcetonitrileHCID 7294Methyl AcrylateHCID 8471TriethylamineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 593348472-(3-Bromo-phenylsulfanyl)-6-phenyl-pyridine

Product 1

HCID 684127523-[3-(6-Phenyl-pyridin-2-ylsulfanyl)-phenyl]-acrylic acid methyl ester

Sources & evidence

ORD record
ord-3b16c4b652f540bea01ddb0f1a3af62f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (2/10)

Reaction notes

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