Thionyl Chloride → HCID 86680251, compound

HRID 921024Notes

Reaction equation

HRID 921024 reaction equation
[C:1]1([C:7]2[CH:8]=[C:9]([CH:13]=[C:14]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)[CH:15]=2)[C:10](O)=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.S(Cl)([Cl:24])=O>CN(C=O)C>[C:1]1([C:7]2[CH:8]=[C:9]([CH:13]=[C:14]([C:16]3[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=3)[CH:15]=2)[C:10]([Cl:24])=[O:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 24386Thionyl ChlorideHCID 411507699710-75-5

Product 1

HCID 86680251HCID 86680251, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideCatalyst

Procedure

Preparation in accordance with Organikum [Practical Organic Chemistry], VEB Deutscher Verlag der Wissenschaften, Berlin, 5th Edition, 1965, page 409, by boiling 3,5-bisphenylbenzoic acid [99710-75-5] with 2 equivalents of thionyl chloride with addition of 2 drops of DMF. Yield: quantitative. Purity: >98% according to 1H-NMR.

Workup

  1. customPreparation in accordance with Organikum [Practical Organic Chemistry], VEB Deutscher Verlag der Wissenschaften, Berlin, 5th Edition, 1965, page 409

Sources & evidence

ORD record
ord-ab5cc7def04b41a69275591904d3fe4e
Source dataset
uspto-grants-2016_03
Patent number
US09273080B2

Reaction notes

Loading…